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MAIN - Materiali Inorganici

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Attività

The research activities of the MAIN group are focused on design, synthesis and characterization of inorganic materials.

In the field of technlogical materials, conductors, semiconductors, superconductors, photocatalyst, biosensors and biomaterials are investigated.

Design includes theoretical calculations and experimental simulation.

Synthesis is focused on alternative ways with respect to the traditional wet procedures, i.e. faster, more efficient, with lower environmental impact, cheaper.

Characterization is performed using a wide variety of experimental techniques and extended to cultural heritage materials.

In this field special attention is drawn to the use of either non-invasive or micro-destructive techniques.

Analyzed materials for cultural heritage include pottery, porcelain, mortar and plaster, metals, paintings, frescoes, enamels, miniatures, inks, photographs, glass, wood and bones.

 

  

Several members of the MAIN group adhere to the Interdepartmental centers

CRISDI (Interdepartmental Center for Crystallorgraphy) and

NIS (Nanostructured Interfaces and Surfaces)

   
   

 Focus of the MAIN group is design, synthesis and characterization of inorganic materials. 

Investigated materials:
- amorphous semiconductor based on Si and Ge
- superconductors based on YBCO and MgB2
- nanostructured metallic materials
- coordination polymers of metals with d10 electronic configuration, for crystal engineering of materials with opto-electronic properties

The synthesis is performed either with traditional methods like solution reactions, and with solvo-thermal, mechanochemical and microwave assisted methods,
X-ray CVD (X-ray induced chemical vapour deposition) 

Analytical techniques:
- Structural and morphological characterization (SEM, Optical myscroscopy, Powder and Single crystal X-ray diffraction, Ion trap mass spectrometry)
- Elemental analysis (micro EDX, portable and micro X-ray fluorescence X)
- Magnetic analysis (magnetic susceptibility and hysteresis cycles)
- Electrical analysis (determination of the resistivity by means of four-point-probe apparatus, even at low temperatures)
- FT-IR spectroscopy, Portable RAMAN

Theoretical methodologies:
- MP2, DFT, CCSDT, QCI, CAS-MCSCF, MRCI (GAUSSIAN and MOLPRO programs)

Micrometric TiO2 commercial materials, either plain or promoted by addition of heterospecies (N, C, F, etc) as substitutes of nanometric TiO2 in photocatalysis applications (tiles, cements, fillers, etc) along the UE guidelines.  

Pollutants can be either in the gas phase (Volatile Organic Compounds-VOCs) or in the liquid phase (aromatics, drugs, etc.)

                                       

A first research line regards both synthesis and characterization of biosensor with non linear optical activity, obtained starting from inorganic salts and organic non centrosymmetric natural compounds, thus of low commercial cost and almost totally non toxic.

Synthesis is carried out both at the solid state and in solution whereas the characterization takes place with the UV-Vis, FT-IR and Raman spectroscopies and with single crysytal and powder X-ray Diffraction. The design of these materials is performed with both DFT and ab initio methods in order to i) model their physical properties, ii) reduce the variety of the non interesting compounds and iii) evidence the most promising ones. Some of the investigation are carried out in collaboration with a research group of the INRIM (Istituto Nazionale di Ricerca Metrologica).                                               

 [Ca(C6H12O6)2(H2O)2]Cl2∙H2O

 [Ca(C6H12O6)(H2O)2]Cl2

 [Ca(C6H12O6)(H2O)3]Cl2

 [Ca(C6H12O6)2(H2O)2]Cl2∙H2O

 [Ca(C6H12O6)(H2O)2]Cl2

 [Ca(C6H12O6)(H2O)3]Cl2

A second research line is Healt, bio and bio-inspired materials (silica nanoparticles; bioactive glasses doped with different inorganic ions and/or metal nanoparticles, NPs, i.e. Mg, Sr, Ga, Cu and Au ions and/or Cu, Au NPs;  etc..) for drug delivery, bone and dental substitution/reparation/implantation etc. This research activity is carried out in collaboration with the SURFIN group.

One of the active research lines within the MAIN group is archaeometric study on several materials in the field of the cultural heritage, both from excavation or from museum context, with a parallel development of the analytical procedures.

Analyzed materials include pottery, porcelain, mortar and plaster, metals, paintings, frescoes, enamels, miniatures, inks, photographs, glass, wood and bones.

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Several collaborations with the Department of Historical Studies are ongoing on ceramic and composite materials from archaeological sites in Piedmont, Sicily, Calabria, Cyprus, Iran and Turkmenistan. A multi-technique approach is adopted with the final aim of a wide technological characterization.

Other projects concern wooden objects, or colored lacquer, produced in Asia, with spectroscopic techniques, studies of archaeological materials from Piedmont Neolithic Age, study of osteological material from Roman and Medieval age.

A third very active area concerns archeometric studies by means of X-ray fluorescence of the different objects of artistic interest. In this field are currently in progress a provenance study of limousin enamels in collaboration with the Palazzo Madama Museum and Galleria Sabauda of Turin, the Museo Leone of Vercelli, the Convento di san Sebastiano (BI) and the Louvre Museum; a study of materials related to the production of illuminated manuscripts, in particular the so-called purple codices, in collaboration with the Biblioteca Nazionale Universitaria, Biblioteca Braidense (MI), Biblioteca Palatina of Parma, Archivio Capitolare of Vercelli and a study of the possible instrumental XRF energy loss for the quantitative determination of glassy systems, in collaboration with the Stazione sperimentale del Vetro of Venezia.

It is just concluded a comprehensive study on eighteenth-century  Piedmontese porcelains in collaboration with the Museo Civico d'Arte Antica di Palazzo Madama, in Torino.

A second project  recently completed concerns the physico-chemical characterization of materials from archaeological excavation conducted by the Università degli Studi di Firenze in the  Kouris river valley (Cyprus).  Archaeometric studies were closely integrated with the archaeological evaluation in order to determine the technologies used by craftsmen, the specific uses of the artifacts and of the buildings.

The analyzed materials includes ceramics, mortar and plaster.

The used techniques range from surface morphological analysis to the chemical, mineralogical and technological characterization and include:

-          Electron Microscopy eventually coupled with elemental microanalysis (SEM-EDX)

-          Optical Miscroscopy

-          Powder and Single Crystal XRD

-          Thermal analysis techniques (TGA, DSC)

-          UV-vis diffuse reflectance spectroscopy and FORS (Fiber Optic Reflectance Spectroscopy)

-          IR

-          Raman

-          Portable and micro XRF

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The MAIN group is involved in several collaborations with other research groups of the Department, of other Departments, Universities and Research Institutions, as well as with other Institutions, in particular in the field of the cultural heritage. Moreover, a collaboration with the Scientific Police of Turin for the characterization of crystalline and semi-crystalline samples of forensic interest, is ongoing.

musée cernuschi  Fondazione Accorsi - Ometto Torino        Logo

MAIN group members possess numerous expertise and are available both to start new collaborations and to perform analyses for third parties.

The group has extensive expertise in inorganic synthesis, performed either with traditional methods like solution reactions, and with solvo-thermal, mechanochemical and microwave assisted methods, x-ray CVD.

With regard to the analysis  great experience is possessed in the vibrational spectroscopy (also with computational modeling at the molecular and crystalline level) of molecular and solid inorganic and organic materials; in single crystal and powders x-ray diffraction, both at high and at low temperature, of organic, inorganic and organometallic compounds.

Finally, extensive practice is held in the characterization of materials in the field of cultural heritage, possibly with non-invasive techniques, and authentication.

 

Progetti

Prodotti della ricerca

Turco, F , Davit, P , Cossio, R , Agostino, A , Operti, L (2017)
Accuracy improvement by means of porosity assessment and standards optimization in SEM-EDS and XRF elemental analyses on archaeological and historical pottery and porcelain.
https://iris.unito.it/handle/2318/1623042

Turco, F, Davit, P , Chelazzi, F , Borghi, A , Bombardieri, L , Operti, L (2016)
Characterization of Late Prehistoric Plasters and Mortars from Erimi - Laonin tou Porakou (Limassol, Cyprus).
https://iris.unito.it/handle/2318/1525268

Turco, F , Davit, P , Borghi, A , Bruno, J , Lippolis, C , Operti, L (2016)
Multi-technique characterization of various artefacts and raw materials from Old Nisa (Turkmenistan): A preliminary study.
https://iris.unito.it/handle/2318/1535321

Turco, F, Davit, P , Maritano, C , Operti, L , Fenoglio, G , Agostino, A (2015)
XRF Characterization Of 18th Century Piedmontese Porcelains From The Palazzo Madama Museum (Torino, Italy).
https://iris.unito.it/handle/2318/1525047

Djellabi, Ridha, Fouzi Ghorab, Mohamed, Bianchi, Claudia Letizia, Cerrato, Giuseppina, Morandi, Sara (2016)
Removal of Crystal Violet and Hexavalent Chromium using TiO2-Bentonite under Sunlight: Effect of TiO2 Content.
https://iris.unito.it/handle/2318/1560653

Stucchi, Marta, Bianchi, Claudia L , Pirola, Carlo, Cerrato, Giuseppina, Morandi, Sara, Argirusis, Christos, Sourkouni, Georgia, Naldoni, Alberto, Capucci, Valentino (2016)
Copper NPs decorated titania: A novel synthesis by high energy US with a study of the photocatalytic activity under visible light.
https://iris.unito.it/handle/2318/1560652

Djellabi, Ridha, Ghorab, Mohamed Fouzi, Bianchi, Claudia Letizia, Cerrato, Giuseppina, Morandi, Sara (2016)
Recovery of hexavalent chromium from water using photoactive TiO2-montmorillonite under sunlight.
https://iris.unito.it/handle/2318/1560654

Mutch, Greg A , Morandi, Sara, Walker, Rebecca, Anderson, James A , Vega-Maza, David, Operti, Lorenza, Cerrato, Giuseppina (2016)
Cation Dependent Carbonate Speciation and the Effect of Water.
https://iris.unito.it/handle/2318/1622285

Mutch, Greg A , Anderson, James A , Walker, Rebecca, Cerrato, Giuseppina, Morandi, Sara, Operti, Lorenza, Vega-Maza, David (2016)
In-situ infrared spectroscopy as a non-invasive technique to study carbon sequestration at high pressure and high temperature.
https://iris.unito.it/handle/2318/1622284

Bianchi, Claudia L , Sacchi, Benedetta, Pirola, Carlo, Demartin, Francesco, Cerrato, Giuseppina, Morandi, Sara, Capucci, Valentino (2016)
Aspirin and paracetamol removal using a commercial micro-sized TiO2 catalyst in deionized and tap water.
https://iris.unito.it/handle/2318/1622286

Signoretto, M , Ghedini, E , Nichele, V , Pinna, F , Casotti, D , Cruciani, G , Aina, V , Martra, G , Cerrato, G (2016)
Formulation of Innovative Hybrid Chitosan/TiO2- and Chitosan/SiO2-Based Drug-Delivery Systems.
https://iris.unito.it/handle/2318/1622884

Bianchi, Claudia L , Pirola, Carlo, Stucchi, Marta, Sacchi, Benedetta, Cerrato, Giuseppina, Morandi, Sara, Di Michele, Alessandro, Carletti, Alessandra, Capucci, Valentino (2016)
A New Frontier of Photocatalysis Employing Micro-Sized TiO2: Air/Water Pollution Abatement and Self-Cleaning/ Antibacterial Applications.
https://iris.unito.it/handle/2318/1622871

Barbero, Margherita, Cadamuro, Silvano, Dughera, Stefano, Ghigo, Giovanni, Marabello, Domenica, Morgante, Pierpaolo (2016)
Efficient alkylation of cyclic silyl enol ethers by diarylmethylium salts.
https://iris.unito.it/handle/2318/1620419

Parisotto, Stefano, Garreffa, Gabriele, Canepa, Carlo, Diana, Eliano, Pellegrino, Francesco, Priola, Emanuele, Prandi, Cristina, Maurino, Valter, Deagostino, Annamaria (2017)
Visible Light Photocatalytic Transformation of ?,?-Unsaturated-N-Tosylhydrazones: a Novel Route to Allylic Sulfones.
https://iris.unito.it/handle/2318/1620346

Priola, Emanuele, Bonometti, Elisabetta, Brunella, Valentina, Operti, Lorenza, Diana, Eliano (2016)
Luminescent coordination polymers of 2,2?-bipyrimidine and mercury(II) salts: a structural and computational study.
https://iris.unito.it/handle/2318/1551323

Diana, Eliano, Gatterer, Karl, Kettle, Sidney F A (2016)
The vibrational spectroscopy of the coordinated azide anion; A theoretical study.
https://iris.unito.it/handle/2318/1551325

Grifasi, Francesca, Priola, Emanuele, Chierotti, Michele R, Diana, Eliano, Garino, Claudio, Gobetto, Roberto (2016)
Vibrational?Structural Combined Study into Luminescent Mixed Copper(I)/Copper(II) Cyanide Coordination Polymers.
https://iris.unito.it/handle/2318/1593049

Mino, L , Borfecchia, E , Agostino, A , Lamberti, C, Truccato, M
Oxygen doping tuning in superconducting oxides by thermal annealing and hard X-ray irradiation.
https://iris.unito.it/handle/2318/1615656

Pascale, Lise, Truccato, Marco, Operti, Lorenza, Agostino, Angelo (2016)
Effect of Al and Ca co-doping, in the presence of Te, in superconducting YBCO whiskers growth.
https://iris.unito.it/handle/2318/1600050

Truccato, Marco, Agostino, Angelo, Borfecchia, Elisa, Mino, Lorenzo, Cara, Eleonora, Pagliero, Alessandro, Adhlakha, Nidhi, Pascale, Lise, Operti, Lorenza, Enrico, Emanuele, De Leo, Natascia, Fretto, Matteo, Martinez-Criado, Gema, Lamberti, Carlo (2016)
Direct-Write X-ray Nanopatterning: A Proof of Concept Josephson Device on Bi2Sr2CaCu2O8+? Superconducting Oxide.
https://iris.unito.it/handle/2318/1559295

L Gozzelino, R Gerbaldo, G Ghigo, F Laviano, M Truccato, A Agostino (2016)
Superconducting and hybrid systems for magnetic field shielding.
https://iris.unito.it/handle/2318/1559292

Priola, Emanuele, Bonometti, Elisabetta, Rabezzana, Roberto, Buscaino, Roberto, Chierotti, Michele R , Operti, Lorenza, Diana, Eliano (2016)
[Ag(PPh3)4][(PPh3)CdCl3], the first monomeric trichlorocadmate complex bonded to a phosphorus ligand: a structural and spectroscopic study in solution and solid state.
https://iris.unito.it/handle/2318/1623673

Soliveri, Guido, Pifferi, Valentina, Annunziata, Rita, Rimoldi, Luca, Aina, Valentina, Cerrato, Giuseppina, Falciola, Luigi, Cappelletti, Giuseppe, Meroni, Daniela (2015)
Alkylsilane?SiO2 Hybrids. A Concerted Picture of Temperature Effects in Vapor Phase Functionalization.
https://iris.unito.it/handle/2318/1521689

Bianchi, Claudia L , Pirola, Carlo, Galli, Federico, Stucchi, Marta, Morandi, Sara, Cerrato, Giuseppina, Capucci, Valentino (2015)
Nano and micro-TiO2 for the photodegradation of ethanol: experimental data and kinetic modelling.
https://iris.unito.it/handle/2318/1521687

M Stucchi, C L Bianchi, C Pirola, S Vitali, G Cerrato, S Morandi, C Argirusis, G Sourkouni, P M Sakkas, V Capucci (2015)
Surface Decoration of Commercial Micro-sized TiO2 by means of High Energy Ultrasound: A Way to Enhance its Photocatalytic Activity Under Visible Light.
https://iris.unito.it/handle/2318/1508504

V Pifferi, G Cappelletti, S Ardizzone, L Falciola, C Di Bari, F Spadavecchia, D Meroni, A Carrà, G Cerrato, S Morandi, E Davoli (2015)
Photo-mineralization of noxious o-toluidine water pollutant by nano-ZnO: The role of the oxide surface texture on the kinetic path.
https://iris.unito.it/handle/2318/157877

Cerrato, Giuseppina, Bianchi, Claudia Letizia, Morandi, Sara, Pirola, Carlo, Stucchi, Marta, Diamanti, Maria Vittoria, Pedeferri, Maria Pia, Capucci, Valentino (2015)
The Role of the Nano/Microstructure in the Case of the Photodegradation of Two Model VOC Pollutants Using Commercial TiO2.
https://iris.unito.it/handle/2318/1521685

C L Bianchi, C Pirola, F Galli, G Cerrato, S Morandi, V Capucci (2015)
Pigmentary TiO2: a challenge for its use as photocatalyst in NOx air purification.
https://iris.unito.it/handle/2318/1506902

M Signoretto, F Menegazzo, F Pinna, M Manzoli, V Aina, G Cerrato, F Boccuzzi (2014)
Oxidative esterification of renewable furfural on gold based catalysts: which is the best support?
https://iris.unito.it/handle/2318/140624

Guido Soliveri, Daniela Meroni, Giuseppe Cappelletti, Rita Annunziata, Valentina Aina, Giuseppina Cerrato, Silvia Ardizzone (2014)
Engineered organic/inorganic hybrids for superhydrophobic coatings by wet and vapour procedures.
https://iris.unito.it/handle/2318/141622

Menegazzo Federica, Signoretto Michela, Pinna Francesco, Manzoli Maela, Aina Valentina, Cerrato Giuseppina, Boccuzzi Flora (2014)
Oxidative esterification of renewable furfural on gold-based catalysts: Which is the best support?
https://iris.unito.it/handle/2318/141626

Valentina Aina, Claudio Magistris, Giuseppina Cerrato, Gianmario Martra, Guido Viscardi, Gigliola Lusvardi, Gianluca Malavasi, Ledi Menabue (2014)
New Formulation of Functionalized Bioactive Glasses to Be Used as Carriers for the Development of pH-Stimuli Responsive Biomaterials for Bone Diseases.
https://iris.unito.it/handle/2318/143640

Valentina Aina, Gianluca Malavasi, Claudio Magistris, Giuseppina Cerrato, Gianmario Martra, Guido Viscardi, Ledi Menabue, Gigliola Lusvardi (2014)
Conjugation of amino-bioactive glasses with 5-aminofluorescein as probe molecule for the development of pH sensitive stimuli-responsive biomaterials.
https://iris.unito.it/handle/2318/143644

V Aina, G Cerrato, C Magistris, G Martra, G Viscardi, E Ghedini, M Signoretto (2014)
TiO2-chitosan hybrid materials as carriers for the development of stimuli-responsive drug delivery systems.
https://iris.unito.it/handle/2318/155289

V Aina, G Cerrato, C Magistris, G Martra, C Morterra, G Viscardi, G Malavasi (2014)
Novel smart bio-nanomaterials for protein immobilization: bioactive glasses containing metal nanoparticles conjugated with proteins.
https://iris.unito.it/handle/2318/155282

Giuseppina Cerrato, Cristina Sabena, Elena Scalenghe (2014)
L?apprendimento nella scuola dell?infanzia. Riflessioni teoriche ed esperienze didattiche.
https://iris.unito.it/handle/2318/149742

Valentina Nichele, Michela Signoretto, Francesco Pinna, Federica Menegazzo, Ilenia Rossetti, Giuseppe Cruciani, Giuseppina Cerrato, Alessandro Di Michele (2014)
Ni/ZrO2 catalysts in ethanol steam reforming: Inhibition of coke formation by CaO-doping.
https://iris.unito.it/handle/2318/141643

R Djellabi, M F Ghorab, G Cerrato, S Morandi, S Gatto, V Oldani, A Di Michele, C L Bianchi (2014)
Photoactive TiO2?montmorillonite composite for degradation of organic dyes in water.
https://iris.unito.it/handle/2318/156522

Claudia L Bianchi, Enrico Colombo, Sara Gatto, Marta Stucchi, Giuseppina Cerrato, Sara Morandi, Valentino Capucci (2014)
Photocatalytic degradation of dyes in water with micro-sized TiO2 as powder or coated on porcelain-grès tiles.
https://iris.unito.it/handle/2318/149732

Giuseppina Cerrato, Serafina Petrocca (2014)
Bambini con le mani in pasta! Percorsi didattici di educazione alimentare dalla scuola dell'infanzia al primo ciclo dell'istruzione.
https://iris.unito.it/handle/2318/149733

C Magistris, V Aina, G Cerrato, G Martra, G Viscardi, G Malavasi, G Lusvardi, L Menabue (2014)
Conjugation of bioactive glasses with organic molecules: a model for the development of new stimuli-responsive biomaterials for bone tumour treatment.
https://iris.unito.it/handle/2318/155288

V Trevisan, A Olivo, F Pinna, M Signoretto, F Vindigni, G Cerrato, C L Bianchi (2014)
C-N/TiO2photocatalysts: Effect of co-doping on the catalyticperformance under visible light.
https://iris.unito.it/handle/2318/149743

C L Bianchi, S Gatto, C Pirola, A Naldoni, A Di Michele, G Cerrato, V Crocellà, V Capucci (2014)
Photocatalytic degradation of acetone, acetaldehyde and toluene in gas-phase: Comparison between nano and micro-sized TiO2.
https://iris.unito.it/handle/2318/141705

C Gamarra, A Agostino, M Aceto, G Fenoglio, M Labate, L Operti (2015)
Influence of degradation in the production of quantitative data by using Portable XRF on glassy matrices of Limousin composition.
https://iris.unito.it/handle/2318/157988

Antoniotti, Paola, Benzi, Paola, Borocci, Stefano, Demaria, Chiara, Giordani, Maria, Grandinetti, Felice, Operti, Lorenza, Rabezzana, Roberto (2015)
Bimolecular Homolytic Substitutions at Nitrogen: An Experimental and Theoretical Study on the Gas-Phase Reactions of Alkyl Radicals with NF3.
https://iris.unito.it/handle/2318/1524250

Marabello, Domenica, Antoniotti, Paola, Benzi, Paola, Canepa, Carlo, Diana, Eliano, Operti, Lorenza, Mortati, Leonardo, Sassi, Maria Paola (2015)
Non-linear optical properties of ?-D-fructopyranose calcium chloride MOFs: an experimental and theoretical approach.
https://iris.unito.it/handle/2318/1524935

Alessia Giordana, Emanuele Priola, Elisabetta Bonometti, Lorenza Operti, Eliano Diana (2015)
Crystal engineering of non-centrosymmetric systems.
https://iris.unito.it/handle/2318/1525496

Antoniotti, Paola, Benzi, Paola, Demaria, Chiara, Operti, Lorenza, Rabezzana, Roberto (2015)
Optical spectroscopic characterization of amorphous germanium carbide materials obtained by X-Ray Chemical Vapor Deposition.
https://iris.unito.it/handle/2318/1526666

F. Turco, A. Agostino, P. Davit, G. Fenoglio, L. Operti, C. Maritano
XRF CHARACTERIZATION OF VINOVO MANUFACTURE PORCELAINS FROM THE PALAZZO MADAMA MUSEUM

http://hdl.handle.net/2318/139060

Davit, P , Turco, F , Coluccia, S , Operti, L , Chelazzi, F , Bombardieri, L (2014)
TECHNOLOGICAL AND COMPOSITIONAL CHARACTERIZATION OF RED POLISHED WARE FROM THE BRONZE AGE KOURIS VALLEY (CYPRUS).
https://iris.unito.it/handle/2318/152014

Eliano Diana, Elisa Maupas, Rosa Boano, Emma Rabino Massa, Bernardo Arriaza
Spectroscopic characterization of ancient human tissue from the Chinchorro mummies
http://hdl.handle.net/2318/148182

Alessandro Pagliero, Lorenzo Mino, Elisa Borfecchia, Marco Truccato, Angelo Agostino, Lise Pascale, Emanuele Enrico, Natascia De Leo, Carlo Lamberti, Gema Martinez-Criado
Doping change in the Bi-2212 superconductor directly induced by a hard X-ray nano-beam
http://hdl.handle.net/2318/148323

M. Aceto, A. Agostino,G. Fenoglio,P. Baraldi,P. Zannini,C. Hofmann,E. Gamillscheg
First analytical evidences of precious colourants on Mediterranean illuminated manuscripts
http://hdl.handle.net/2318/123200

Eliano Diana, Giuliana Gervasio, Emanuele Priola, Elisabetta Bonometti
A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n.
http://hdl.handle.net/2318/151993

Gozzzelino l., Gerbaldo R., Ghigo G., Laviano F., Agostino A., Bonometti E., Chiampi M., Manzin A., Ziliberti L., - DC shielding properties of coaxial MgB2/Fe cups- 2013, IEEE Transactions of applied Superconductivity, 23, (3), article number: 8201305

C. Demaria, A. Arrais, E. Boccaleri, P. Benzi, G. Gatti, S. Cantamessa, L. Operti
Growth of Forests of Regular-Shaped Carbon Nanofibers Yielded by Acetylene Thermal Chemical Vapour Deposition at Low Temperatures on Conventional Copper Foils
http://hdl.handle.net/2318/150447

Paola Antoniotti, Paola Benzi, Lorenza Operti, Roberto Rabezzana, Stefano Borocci, Maria Giordani, Felice Grandinetti
Ion chemistry of sulfuryl fluoride: An experimental and theoretical study on gas-phase reactions involving neutral and ionized SO2F2
http://hdl.handle.net/2318/139268

Chiara Demaria, Paola Benzi, Aldo Arrais, Elena Bottizzo, Paola Antoniotti, Roberto Rabezzana, Lorenza Operti
Growth and thermal annealing of amorphous germanium carbide obtained by X-ray chemical vapor deposition
http://hdl.handle.net/2318/136716

Paola Antoniotti, Paola Benzi, Elena Bottizzo, Lorenza Operti, Roberto Rabezzana, Stefano Borocci, Maria Giordani, Felice Grandinetti
(HNg+)(OH2) complexes (Ng = He?Xe): An ab initio and DFT theoretical investigation
http://hdl.handle.net/2318/139267

L. Calore, M.M. Rahman Khan, S. Cagliero, A. Agostino, M. Truccato, L. Operti
Al doping influence on crystal growth, structure and superconducting properties of Y(Ca)Ba2Cu3O7y whiskers
http://hdl.handle.net/2318/133117

L. Operti, R. Rabezzana, F. Turco, S. Borocci, M. Giordani, F. Grandinetti
Germyl cations with Ge-S bonds: an experimental and theoretical study on the gaseous FnGe(SH)3-n+ (n = 0 2)
http://hdl.handle.net/2318/113074

L. Operti, R. Rabezzana, F. Turco, S. Borocci, M. Giordani, F. Grandinetti
Experimental and theoretical investigation of gas phase FnGe(SH)3-n+ (n = 0 - 2) ion species
http://hdl.handle.net/2318/116734

Paola ANTONIOTTI, Paola BENZI, Stefano BOROCCI, Felice GRANDINETTI, Lorenza OPERTI, Roberto RABEZZANA
A joint theoretical-experimental investigation of the gas-phase reactions of alkyl radicals with NF3: bimolecular homolytic substitution vs F-atom abstraction
http://hdl.handle.net/2318/117784

Chiara DEMARIA, Aldo ARRAIS, Paola BENZI, Enrico BOCCALERI, Lorenza OPERTI
Massive synthesis of high purity Ge nanowires obtained by combined X-ray chemical vapour deposition of GeH4 and thermal treatment techniques
http://hdl.handle.net/2318/119761

Chiara DEMARIA, Paola BENZI, Lorenza OPERTI
X-ray chemical vapour deposition of amorphous germanium carbide: growth processes correlated with structural features
http://hdl.handle.net/2318/119762

Paola Benzi, Elena Bottizzo, Chiara Demaria, Lorenza Operti
Investigation on annealed amorphous germanium carbide prepared by X-Ray radiolysis of GeH4/C2H2 gaseous mixtures.
http://hdl.handle.net/2318/78742

S. Berto, P. G. Daniele, E. Diana, E. Laurenti, E. Prenesti
Thermodynamic, spectroscopic and DFT description of oxidovanadium(IV) complexes with malate and tartrate in aqueous solution
http://hdl.handle.net/2318/142856

Tamara Slatineanu, Eliano Diana, Valentin Nica,Victor Oancea, Ovidiu F. Caltun, Alexandra R. Iordan, Mircea N. Palamaru
The influence of the chelating/combustion agents on the structure and magnetic properties of zinc ferrite
http://hdl.handle.net/2318/119459

Marco Blangetti, Annamaria Deagostino, Giuliana Gervasio, Domenica Marabello, Cristina Prandi, Paolo Venturello
Superbase promoted synthesis of dienamides as useful intermediates for the synthesis of a-ketoamides, g-lactams and cyclic imino ethers
http://hdl.handle.net/2318/88140

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